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Paris Saint-Germain's hopes of a domestic double this season ended on Wednesday as Ligue 1 minnows Evian eliminated them 4-1 on penalties after their quarter-final ended 1-1 after extra-time.
PSG - who were knocked out of the Champions League last week by Barcelona - had taken the lead through Javier Pastore in the eighth minute.
However, Tunisian international Saber Khlifa nipped in behind a static David Beckham two minutes from half-time to level.
Neither side could gain the upper hand in the second-half and extra-time was only memorable for the straight red card for Thiago Motta for a foul on Cedric Barbosa two minutes from the final whistle.
PSG endured a dreadful penalty shoot-out with Zlatan Ibrahimovic and Thiago Silva missing the first two spot kicks for the visitors.
Barbosa was to have the last laugh as he whacked home his spot kick to seal the Ligue 1 strugglers a place in the last four and end PSG's hopes of a ninth Cup trophy.
Earlier Bordeaux had to come from behind against Ligue 2 side Lens to win 3-2 and book their place in the semi-finals.
Bordeaux had Malian forward Cheick Diabate to thank as a double from him propelled them into their first appearance in the last four of the competition since 2003.
On Tuesday, Ligue 1 outsiders Lorient and Troyes had progressed to the semi-finals.
Jeremie Aliadiere's stoppage-time strike took Lorient through as they beat League Cup finalists Saint-Etienne 2-1 away which gives them a chance of winning the Cup for only the second time in their history.
Former Arsenal striker Aliadiere's 18th goal of the season sealed Saint-Etienne's first defeat of 2013 and also put paid to their dreams of winning a domestic Cup double.
They could gain quick compensation, however, should they beat Rennes in Saturday's League Cup final encounter at the Stade de France.
In a meeting of two clubs in the Ligue 1 relegation zone, Troyes beat Nancy 3-0, with Jeremie Brechet, Julien Faussurier and Fabien Camus all scoring in the second half.